327956

(1R)-(+)-Nopinone

98%

• Synonym(s): 6,6-Dimethylbicyclo[3.1.1]heptan-2-one
• Empirical Formula (Hill Notation): C₉H₁₄O
• CAS Number: 38651-65-9
• Molecular Weight: 138.21
• MDL number: MFCD08447116
• UNSPSC Code: 12352115
• PubChem Substance ID: 24859704
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 98%
• form: liquid
• optical activity: [α]20/D +16°, neat
• refractive index: n20/D 1.479 (lit.)
• bp: 209 °C (lit.)
• density: 0.981 g/mL at 25 °C (lit.)
• functional group: ketone
• storage temp.: 2-8°C
• SMILES string: CC1(C)[C@H]2CCC(=O)[C@@H]1C2
• InChI: 1S/C9H14O/c1-9(2)6-3-4-8(10)7(9)5-6/h6-7H,3-5H2,1-2H3/t6-,7-/m0/s1
• InChI key: XZFDKWMYCUEKSS-BQBZGAKWSA-N

Description

Application

(1R)-(+)-Nopinone may be used in the preparation of a chiral annulated indene derivative, which can be a potentially useful chiral ligand for transition metal complexes in asymmetric transformations. It may also react with secondary amines in cyclohexane to form the corresponding enamines.

Safety Information

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 167.0 °F - closed cup
• Flash Point(C): 75 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves