329118

Geranyl bromide

95%

• Synonym(s): trans-1-Bromo-3,7-dimethyl-2,6-octadiene
• Linear Formula: (CH₃)₂C=CHCH₂CH₂C(CH₃)=CHCH₂Br
• CAS Number: 6138-90-5
• Molecular Weight: 217.15
• Beilstein: 1703631
• EC Number: 228-123-7
• MDL number: MFCD00000243
• UNSPSC Code: 12352100
• PubChem Substance ID: 24859770
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 95%
• form: liquid
• refractive index: n20/D 1.504 (lit.)
• bp: 101-102 °C/12 mmHg (lit.)
• density: 1.094 g/mL at 25 °C (lit.)
• functional group: alkyl halide; bromo
• storage temp.: 2-8°C
• SMILES string: C\C(C)=C\CC\C(C)=C\CBr
• InChI: 1S/C10H17Br/c1-9(2)5-4-6-10(3)7-8-11/h5,7H,4,6,8H2,1-3H3/b10-7+
• InChI key: JSCUZAYKVZXKQE-JXMROGBWSA-N

Description

General description

Geranyl bromide undergoes palladium catalyzed cross-coupling reaction with aryl and alkenylgold(I) phosphanes.

Application

Geranyl bromide was used in synthesis of baicalein and 3,7-dihydroxyflavone derivatives. It was also used in synthesis of potential flavonoidic modulators of P-glycoprotein activity.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 167.0 °F - closed cup
• Flash Point(C): 75 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves