423602

Ethyl cis-3-iodoacrylate

98%

• Linear Formula: ICH=CHCO₂C₂H₅
• CAS Number: 31930-36-6
• Molecular Weight: 226.01
• MDL number: MFCD00209584
• UNSPSC Code: 12352100
• PubChem Substance ID: 24866512
• NACRES: NA.22

Properties

• Quality Level: 200
• Assay: 98%
• form: liquid
• refractive index: n20/D 1.533 (lit.)
• bp: 85 °C/20 mmHg (lit.)
• density: 1.765 g/mL at 25 °C (lit.)
• functional group: ester; iodo
• storage temp.: 2-8°C
• SMILES string: [H]\C(I)=C(/[H])C(=O)OCC
• InChI: 1S/C5H7IO2/c1-2-8-5(7)3-4-6/h3-4H,2H2,1H3/b4-3-

Description

General description

Ethyl cis-3-iodoacrylate (cis-ethyl-β-iodoacrylate, ethyl (Z)-β-iodoacrylate) is Z-vinyl iodide derivative.[1] It is reported to be prepared from ethyl propiolate by treating with sodium iodide.[2] Its Suzuki coupling reaction with cyclic vinyl boronic acids has been studied.[3]

Application

Ethyl cis-3-iodoacrylate may be used in the synthesis of the following:

• vinyl sulfides[1]
• (Z)-1-iodohept-1-en-3-ol[2]
• (E)-1-iodohept-1-en-3-ol[2]
• (Z)-β-iodoacrolein[2]
• 6-oxo-M₁Guo[4]

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 210.2 °F - closed cup
• Flash Point(C): 99 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves