539406

Methyl 6-bromo-2-naphthoate

98%

• Linear Formula: BrC₁₀H₆CO₂CH₃
• CAS Number: 33626-98-1
• Molecular Weight: 265.10
• MDL number: MFCD00100408
• UNSPSC Code: 12352100
• PubChem Substance ID: 24878396
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 98%
• mp: 123-126 °C (lit.)
• functional group: bromo; ester
• SMILES string: COC(=O)c1ccc2cc(Br)ccc2c1
• InChI: 1S/C12H9BrO2/c1-15-12(14)10-3-2-9-7-11(13)5-4-8(9)6-10/h2-7H,1H3
• InChI key: JEUBRLPXJZOGPX-UHFFFAOYSA-N

Description

General description

Methyl 6-bromo-2-naphthoate undergoes aromatic Finkelstein reaction followed by hydrolysis to afford 6-iodo-2-naphthoic acid.

Application

Methyl 6-bromo-2-naphthoate may be used to synthesize:

• 6-vinyl-2-naphthalencarbaldehyde
• methyl 6-(3-tert-butyl-4-methoxyphenyl)-2-naphthoate
• methyl 6-[3-tert-butyl-4-[(tert-butyldiethylsilyl)oxy]-phenyl]-2-naphthoate
• methyl 6-[3-(1-adamantyl)-4-[(tert-butyldimethylsilyl)-oxy]phenyl]-2-naphthoate
• methyl 6-[3-(1-adamantyl)-4-[[(2,3-dimethyl-1,3-dioxolan-4-yl)methylloxy]phenyl]-2-naphthoate
• 2-bromo-6-(bromomethyl)naphthalene

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves