552844

3-Amino-6-bromopyridine

97%

• Empirical Formula (Hill Notation): C₅H₅BrN₂
• CAS Number: 13534-97-9
• Molecular Weight: 173.01
• MDL number: MFCD01646116
• UNSPSC Code: 12352100
• PubChem Substance ID: 24879291
• NACRES: NA.22

Properties

• Quality Level: 200
• Assay: 97%
• form: solid
• mp: 74-76 °C (lit.)
• functional group: bromo
• SMILES string: Nc1ccc(Br)nc1
• InChI: 1S/C5H5BrN2/c6-5-2-1-4(7)3-8-5/h1-3H,7H2
• InChI key: XTHKRYHULUJQHN-UHFFFAOYSA-N

Description

General description

3-Amino-6-bromopyridine can be synthesized via bromination of 3-aminopyridine using N-bromosuccinimide in acetonitrile.

Application

3-Amino-6-bromopyridine may undergo polymerization via Buchwald–Hartwig amination in the presence of sodium tert-butoxide and XPhos(2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl) ligand yielding para-linked and meta-linked polyaminopyridines.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves