678023

4,7-Dimethoxy-1,10-phenanthroline

97%

• Synonym(s): 4,7-Dimethoxy-1,10-phenanthrolin
• Empirical Formula (Hill Notation): C₁₄H₁₂N₂O₂
• CAS Number: 92149-07-0
• Molecular Weight: 240.26
• MDL number: MFCD00233883
• UNSPSC Code: 12352300
• PubChem Substance ID: 24885413
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 97%
• form: solid
• reaction suitability: reagent type: ligand
• mp: 197-212 °C
• SMILES string: COc1ccnc2c1ccc3c(OC)ccnc23
• InChI: 1S/C14H12N2O2/c1-17-11-5-7-15-13-9(11)3-4-10-12(18-2)6-8-16-14(10)13/h3-8H,1-2H3
• InChI key: ZPGVCQYKXIQWTP-UHFFFAOYSA-N

Description

General description

4,7-Dimethoxy-1,10-phenanthroline is an organic compound that is used as an efficient ligand in organic synthesis. It is used in the N-arylation of imidazole with aryl iodides and bromides in the presence of copper catalysts. Various hindered and functionalized imidazoles and aryl halides were converted using this catalyst.

Application

Ligand for Cu-catalzyed N-arylation of imidazoles

Safety Information

• Pictograms: GHS05,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H302,H318,H400
• Precautionary Statements: P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves