926094

(R)-RUCY^™-XylBINAP

Takasago

• Synonym(s): RuCl[(R)-daipena][(R)-xylbinap]
• Empirical Formula (Hill Notation): C₇₁H₇₃ClN₂O₂P₂Ru
• CAS Number: 1384974-38-2
• Molecular Weight: 1184.82
• MDL number: MFCD20261161
• UNSPSC Code: 12352116
• NACRES: NA.22

Properties

• Quality Level: 100
• form: powder
• reaction suitability: reagent type: ligand
• functional group: phosphine
• SMILES string: [Ru+]c9c(ccc(c9)OC)C(N)([C@H](N)C(C)C)c%10ccc(cc%10)OC.P(c8cc(cc(c8)C)C)(c7cc(cc(c7)C)C)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5cc(cc(c5)C)C)c4cc(cc(c4)C)C)cccc3.[Cl-]
• InChI: 1S/C52H48P2.C19H25N2O2.ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-
• InChI key: VBDGCLWXZBVBHR-LOJLRZLHSA-M

Description

Application

(R)-RUCY^™-XylBINAP is a ruthenabicyclic complex that shows excellent activity in the asymmetric hydrogenation of ketones.

Other Notes

Chiral Ruthenabicyclic Complexes: Precatalysts for Rapid, Enantioselective, and Wide-Scope Hydrogenation of Ketones

Legal Information

Product of Takasago.

For research and development purposes only. PCT/JP2010/072838

RUCY is a trademark of Takasago Intl. Corp.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable