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8.52259

Sigma-Aldrich

(9-Fluorenylmethyl) chloroformate

Novabiochem®

Synonym(s):

(9-Fluorenylmethyl) chloroformate, (9-Fluorenylmethyl) chloroformate, Chloroformic acid 9-fluorenmethyl ester, Chloroformic acid 9-fluorenylmethyl ester, FMOCCl

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About This Item

Empirical Formula (Hill Notation):
C15H11ClO2
CAS Number:
Molecular Weight:
258.70
MDL number:
UNSPSC Code:
12352107
EC Index Number:
249-313-6
NACRES:
NA.22
Assay:
≥98.0% (HPLC)
Application(s):
peptide synthesis
Pricing and availability is not currently available.
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Quality Level

product line

Novabiochem®

Assay

≥98.0% (HPLC)

form

powder

manufacturer/tradename

Novabiochem®

mp

60-63 °C

application(s)

peptide synthesis

storage temp.

2-8°C

SMILES string

ClC(=O)OCC1c2c(cccc2)c3c1cccc3

InChI

1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2

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This Item
8.008818.18203160512
Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

assay

≥98.0% (HPLC)

assay

-

assay

-

assay

97%

application(s)

peptide synthesis

application(s)

-

application(s)

peptide synthesis

application(s)

peptide synthesis

form

powder

form

liquid

form

powder

form

solid

mp

60-63 °C

mp

-81 °C, −81 °C (lit.)

mp

60-63 °C

mp

62-64 °C (lit.)

product line

Novabiochem®

product line

-

product line

-

product line

-

General description

Reagent for introduction of the Fmoc protecting group [1].

Literature references

[1] L.A.Carpino et al. (1987) Acc. Chem. Res., 20, 401.

Analysis Note

Colour (visual): white to slight yellow to beige
Appearance of substance (visual): powder
Assay (HPLC, area%): ≥ 98.0 % (a/a)
Melting range (lower value): ≥ 60 °C
Melting range (upper value): ≤ 64 °C
Identity (IR): passes test

Legal Information

Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Shiffler D, et al.
IEEE transactions on nuclear science, 29(3), 445-451 (2001)
Olga Nazarenko et al.
Inorganic chemistry, 56(19), 11552-11564 (2017-09-13)
Interest in hybrid organic-inorganic lead halide compounds with perovskite-like two-dimensional crystal structures is growing due to the unique electronic and optoelectronic properties of these compounds. Herein, we demonstrate the synthesis, thermal and optical properties, and calculations of the electronic band
Cong Chen et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 6(11), 1802046-1802046 (2019-06-11)
Photovoltaic devices employing lead halide perovskites as the photoactive layer have attracted enormous attention due to their commercialization potential. Yet, there exists challenges on the way to the practical use of perovskite solar cells (PSCs), such as light stability and
Taehwan Jun et al.
Advanced materials (Deerfield Beach, Fla.), 30(43), e1804547-e1804547 (2018-09-15)
Halide perovskites, including CsPbX3 (X = Cl, Br, I), have gained much attention in the field of optoelectronics. However, the toxicity of Pb and the low photoluminescence quantum yield (PLQY) of these perovskites hamper their use. In this work, new

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