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Key Documents

M3634

Sigma-Aldrich

Manganese(II) chloride tetrahydrate

ReagentPlus®, ≥99%

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About This Item

Linear Formula:
MnCl2 · 4H2O
CAS Number:
Molecular Weight:
197.91
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21
form:
powder

Quality Level

product line

ReagentPlus®

Assay

≥99%

form

powder

pH

3.5-6 (25 °C, 50 g/L)

mp

58 °C (lit.)

SMILES string

Cl[Mn]Cl.[H]O[H].[H]O[H].[H]O[H].[H]O[H]

InChI

1S/2ClH.Mn.4H2O/h2*1H;;4*1H2/q;;+2;;;;/p-2

InChI key

CNFDGXZLMLFIJV-UHFFFAOYSA-L

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General description

Manganese(II) chloride tetrahydrate is the tetrahydrate form of manganese(II) chloride. It is used in the preparation of manganese-based hybrid compounds.

Application

Manganese(II) chloride tetrahydrate can be used:      
  • As a promoter to synthesize dihydropyrimidin-2(1H)-ones by the condensation of aldehyde, β-dicarbonyl compounds, and urea under microwave conditions.      
  • As a catalyst to synthesize dihydro-2-oxypyrrole derivatives via one-pot four-component domino condensation of dialkyl acetylenedicarboxylate, formaldehyde, and amines.     
  • To synthesize active manganese oxide with potential application as an oxidant in organic synthesis.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2

Target Organs

Brain

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flash Point(F)

does not flash

Flash Point(C)

does not flash


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