254274
Lithium hydroxide monohydrate
99.95% trace metals basis
Synonym(s):
Lithine hydrate
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About This Item
Linear Formula:
LiOH · H2O
CAS Number:
Molecular Weight:
41.96
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Assay:
99.95% trace metals basis
Form:
crystalline
Quality Level
Assay
99.95% trace metals basis
form
crystalline
reaction suitability
core: lithium
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impurities
≤550.0 ppm Trace Metal Analysis
application(s)
battery precursors
catalysts
material synthesis precursor
greener alternative category
SMILES string
[Li+].O.[OH-]
InChI
1S/Li.2H2O/h;2*1H2/q+1;;/p-1
InChI key
GLXDVVHUTZTUQK-UHFFFAOYSA-M
General description
Lithium hydroxide monohydrate is a strongly alkaline crystalline solid soluble in water. It is prepared industrially by recovering it from spodumene or by evaporating a solution prepared by reacting calcium hydroxide and lithium carbonate. It is mainly used in the synthesis of cathode materials for lithium-ion batteries, such as lithium cobalt oxide (LiCoO2) and lithium iron phosphate. It is also preferred over lithium carbonate for producing lithium nickel manganese cobalt oxides.
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Application
Lithium hydroxide monohydrate can be used mainly for the synthesis of cathode materials for Lithium-ion batteries:
- To synthesize Olivine LiFePO4 nanoplates with different crystal orientations by glycol-based solvothermal process. It demonstrated that the crystal orientation of cathode nanoplates plays an important role in the performance.
- As a precursor for the synthesis of LiFePO4 platelets under hydrothermal synthesis conditions. It exhibited homogeneous particle size distribution, greater electrochemical performances and cycle life, and morphology control.
- To synthesize Ni-rich Li[NixCoyMn1–x–y]O2 gradient cathodes (NCM). These cathodes exhibited enhanced cycling and chemical stability due to their strong crystallographic texture, unique particle morphology, and highly correlated particle orientation.
- As a precursor to prepare porous salt hydrate-based composites for low-temperature thermochemical heat storage.
- As an electrolyte additive in lithium-ion batteries.
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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