424757

trans-4-Methyl-β-nitrostyrene

98%

• Linear Formula: CH₃C₆H₄CH=CHNO₂
• CAS Number: 5153-68-4
• Molecular Weight: 163.17
• MDL number: MFCD00024828
• UNSPSC Code: 12352100
• PubChem Substance ID: 24866588
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 98%
• form: solid
• mp: 102-104 °C (lit.)
• functional group: amine; nitro
• storage temp.: 2-8°C
• SMILES string: [H]\C(=C(\[H])[N+]([O-])=O)c1ccc(C)cc1
• InChI: 1S/C9H9NO2/c1-8-2-4-9(5-3-8)6-7-10(11)12/h2-7H,1H3/b7-6+
• InChI key: JSPNBERPFLONRX-VOTSOKGWSA-N

Description

General description

trans-4-Methyl-β-nitrostyrene ((E)-1-methyl-4-(2-nitrovinyl)benzene) is a nitrolefin. Its asymmetric Michael addition with benzaldehyde in the presence of silylated pyrrolidine catalyst has been reported. Its hydrogenation in the presence of Pd(II) complexes of (Z)-2-((quinolin-3-ylimino)methyl)phenol as catalyst has been studied.

Application

trans-4-Methyl-β-nitrostyrene may be used as a reagent in the synthesis of N-benzylpyrrolomorphinans and 4-oxo-2-aryl-4H-chromene-3-carboxylate derivatives.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves