142719

Phenyl benzoate

99%

• 동의어(들): Benzoic acid phenyl ester
• Linear Formula: C₆H₅CO₂C₆H₅
• CAS Number: 93-99-2
• Molecular Weight: 198.22
• Beilstein: 1566346
• EC Number: 202-293-2
• MDL number: MFCD00003072
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24848534
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 99%
• 양식: solid
• bp: 298-299 °C (lit.)
• mp: 68-70 °C (lit.)
• solubility: alcohol: freely soluble (hot); diethyl ether: slightly soluble; water: insoluble
• 작용기: ester; phenoxy; phenyl
• SMILES string: O=C(Oc1ccccc1)c2ccccc2
• InChI: 1S/C13H10O2/c14-13(11-7-3-1-4-8-11)15-12-9-5-2-6-10-12/h1-10H
• InChI key: FCJSHPDYVMKCHI-UHFFFAOYSA-N

설명

일반 설명

Phenyl benzoate is a phenyl ester of benzoic acid. Crystal structure of phenyl benzoate has been determined from 844 microdensitometer-measured intensities. All bond lengths and angles were reported to be normal. Phenyl benzoate undergoes Fries rearrangement catalyzed by heteropoly acids to yield the acylated phenols and esters.

Phenyl benzoate serves as a precursor that undergoes the intramolecular biaryl coupling reaction to produce the intermediate for the synthesis of (−)-steganone.

애플리케이션

Phenyl benzoate was used in the synthesis of soluble polyimides using dianhydride/diamine derivatives.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H302,H315
• 예방조치 성명서: P264 - P270 - P280 - P301 + P312 - P302 + P352 - P332 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Skin Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves