167150

1-Bromo-4-nitrobenzene

99%

• 동의어(들): 1-Bromo-4-nitrobenzene, 1-Nitro-4-bromobenzene, 4-Bromo-1-nitrobenzene, 4-Nitro-1-bromobenzene, 4-Nitrobromobenzene, 4-Nitrophenyl bromide, p-Bromonitrobenzene, p-Nitrophenyl bromide
• Linear Formula: BrC₆H₄NO₂
• CAS Number: 586-78-7
• Molecular Weight: 202.01
• Beilstein: 636964
• EC Number: 209-583-8
• MDL number: MFCD00007280
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24850195
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 99%
• 양식: solid
• bp: 255-256 °C (lit.)
• mp: 124-126 °C (lit.)
• 작용기: bromo; nitro
• SMILES string: [O-][N+](=O)c1ccc(Br)cc1
• InChI: 1S/C6H4BrNO2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H
• InChI key: ZDFBKZUDCQQKAC-UHFFFAOYSA-N

설명

일반 설명

Electrochemical reduction of 1-bromo-4-nitrobenzene at zinc microelectrodes in ionic liquid has been investigated by cyclic voltammetry. 1-Bromo-4-nitrobenzene undergoes palladium-catalyzed Stille cross coupling reaction with furan-2-yltributyltin using Dabco(triethylenediamine) as ligand. It reacts with p-cresol to yield 1-methyl-4-(4-nitrophenoxy)benzene.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H302
• 예방조치 성명서: P264 - P270 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves