208353

Molybdenum(V) chloride

95%

• 동의어(들): Molybdenum pentachloride, Pentachloromolybdenum
• Linear Formula: MoCl₅
• CAS Number: 10241-05-1
• Molecular Weight: 273.21
• MDL number: MFCD00003467
• UNSPSC 코드: 12352302
• PubChem Substance ID: 24852509
• NACRES: NA.23

속성

• vapor pressure: 1.75 mmHg ( 25 °C); 131 mmHg ( 250 °C)
• Quality Level: 100
• 분석: 95%
• 양식: powder
• 반응 적합성: core: molybdenum; reagent type: catalyst
• 불순물: <0.5% insoluble matter
• bp: 268 °C (lit.)
• mp: 194 °C (lit.)
• density: 2.928 g/mL at 25 °C (lit.)
• SMILES string: Cl[Mo](Cl)(Cl)(Cl)Cl
• InChI: 1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5
• InChI key: GICWIDZXWJGTCI-UHFFFAOYSA-I

설명

일반 설명

Molybdenum(V)chloride is a Lewis acid widely used as a catalyst and reagent in many organicreactions. It can be prepared by direct chlorination of molybdenum metal or byrefluxing thionyl chloride and MoO₃.

애플리케이션

Molybdenum(V) chloride can be used as an efficient catalyst for:

• Condensation of nitrobenzene with alcohols and C-C coupling of alkenyllithium reagents.
• Direct amidation of benzylic alcohols with sulfonamides and carbamates.

It can be used for the chlorination of alkyl halides, alkenes, and alkynes.

It can also be used as aprecursor to synthesize alumina/molybdenum nanocomposites and methylenemolybdenumreagents for chemoselective carbonyl alkenation.

안전성 정보

• 픽토그램: GHS08,GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314,H351
• 예방조치 성명서: P201 - P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable