208523

Ruthenium(III) chloride

Ru content 45-55%

• 동의어(들): Ruthenium trichloride
• Linear Formula: RuCl₃
• CAS Number: 10049-08-8
• Molecular Weight: 207.43
• EC Number: 233-167-5
• MDL number: MFCD00011208
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24852520
• NACRES: NA.22

속성

• Quality Level: 200
• 양식: solid
• 반응 적합성: core: ruthenium; reagent type: catalyst; reaction type: Atom Transfer Radical Polymerization (ATRP)
• density: 3.11 g/mL at 25 °C (lit.)
• SMILES string: Cl[Ru](Cl)Cl
• InChI: 1S/3ClH.Ru/h3*1H;/q;;;+3/p-3
• InChI key: YBCAZPLXEGKKFM-UHFFFAOYSA-K

설명

일반 설명

Ruthenium(III) chloride is a chemical compound, that can be used as a mild Lewis acid catalyst for the acetalization of aldehydes, acetalization of alcohols, and conversion of ketoximes to amides. Additionally, it can also be used as a precursor to synthesize Ru nanoparticles.

애플리케이션

Ruthenium(III) chloride is used as a catalyst:

• In the synthesis of β‐amino alcohols by nucleophilic opening of epoxides with anilines.
• In the acetylation of varies of phenols, alcohols, thiols, and amines under mild conditions.
• In the synthesis of α‐aminonitriles by mixing aldehydes, amines, and trimethylsilyl cyanides.

기타 정보

insoluble form

안전성 정보

• 픽토그램: GHS05,GHS07,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H302,H314,H411
• 예방조치 성명서: P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
• Storage Class Code: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges