209058

Rhodium(II) acetate dimer

powder

• 동의어(들): Rh₂(OAc)₄, Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
• Linear Formula: Rh₂(OOCCH₃)₄
• CAS Number: 15956-28-2
• Molecular Weight: 441.99
• EC Number: 240-084-8
• MDL number: MFCD00003538
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24852229
• NACRES: NA.22

속성

• 양식: powder
• Quality Level: 200
• 반응 적합성: core: rhodium; reagent type: catalyst
• SMILES string: CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O
• InChI: 1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4
• InChI key: SYBXSZMNKDOUCA-UHFFFAOYSA-J

설명

일반 설명

Rhodium(II) acetate dimer is an effective catalyst for carbenoid reactions, hydrocarbon oxidation, hydroboration, and nitrene reactions.

애플리케이션

Effective catalyst for ylide formation.

Homogeneous catalyst.

Used in an efficient synthesis of ß-hydroxy-α-arylacrylates involving the decomposition of diazoetster intermediates with concomitant 1,2-arylmigration.

포장

Bottomless glass bottle. Contents are inside inserted fused cone.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319
• 예방조치 성명서: P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)