215554

Copper(I) iodide

99.999% trace metals basis

• 동의어(들): Cuprous iodide
• 실험식(Hill 표기법): CuI
• CAS Number: 7681-65-4
• Molecular Weight: 190.45
• EC Number: 231-674-6
• MDL number: MFCD00010978
• UNSPSC 코드: 12352302
• eCl@ss: 38150105
• PubChem Substance ID: 24852902
• NACRES: NA.23
• solubility: dilute aqueous acid: insoluble(lit.)

속성

• vapor pressure: 10 mmHg ( 656 °C)
• Quality Level: 200
• 분석: 99.999% trace metals basis
• 양식: powder and chunks
• 반응 적합성: core: copper
• 불순물: ≤15.0 ppm Trace Metal Analysis
• bp: 1290 °C/1 atm (decomp)(lit.)
• mp: 605 °C (lit.)
• solubility: dilute aqueous acid: insoluble(lit.)
• density: 5.62 g/mL at 25 °C (lit.)
• SMILES string: [Cu+].[I-]
• InChI: 1S/Cu.HI/h;1H/q+1;/p-1
• InChI key: LSXDOTMGLUJQCM-UHFFFAOYSA-M

설명

애플리케이션

Copper(I) iodide can be used as a catalyst for:

• For arylation of pyrazole and derivatives by coupling arenediazonium species under mild and ligand-free conditions.
• Selective cross-coupling of dibromo alkenes and heteronucleophiles which leads to numerous building blocks such as 1-bromoenamides, ynamides, ketene N, N-acetals, 1-bromoenol ethers, ynol ethers, ketene O, O-acetals, and vinyl phosphonates.
• Stereospecific and the regioselective reaction of silacyclopropanes with carbonyl compounds.

It can also be used as a starting material in the preparation of diphenylphosphinepyridine-derivatives (PyrPHOS)-copper iodide complexes which are suitable for use in OLEDs.

특징 및 장점

• Low toxicity
• Mild reaction condition
• High purity ensures reproducibility and avoids cocatalysis by contaminants.

안전성 정보

• 픽토그램: GHS08,GHS05,GHS07,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H302,H315,H317,H318,H372,H410
• 예방조치 성명서: P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P314
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral
• 표적 기관: Thyroid
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves