255920

1,1′-(Azodicarbonyl)dipiperidine

99%

• 동의어(들): 1,1′-Azobis(N,N-pentamethyleneformamide), ADD, Azodicarboxylic acid dipiperidide, NSC 356027, SR 4077
• 실험식(Hill 표기법): C₁₂H₂₀N₄O₂
• CAS Number: 10465-81-3
• Molecular Weight: 252.31
• Beilstein: 261917
• MDL number: MFCD00010111
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24855495
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 99%
• 양식: solid
• mp: 134-136 °C (lit.)
• 작용기: azo
• SMILES string: O=C(\N=N\C(=O)N1CCCCC1)N2CCCCC2
• InChI: 1S/C12H20N4O2/c17-11(15-7-3-1-4-8-15)13-14-12(18)16-9-5-2-6-10-16/h1-10H2/b14-13+
• InChI key: OQJBFFCUFALWQL-BUHFOSPRSA-N

설명

애플리케이션

Reactant for preparation of:

• Polyfluoroalkylated tripyrazolylmethane ligands

• (-)-Hygromycin A via Mitsunobu glycosylation
• Optically active α,α-disubstituted amino acids via Mitsunobu reaction
• Aza-β-lactams through [2+2] cycloaddition reactions
• Glycosyl disulfides
• Pyridine ether PPAR agonists
• S-glycosyl amino acid building blocks for combinatorial neoglycopeptide synthesis
• Histamine H3 receptor antagonists

Reactant for:

• Mitsunobu inversion reactions

Used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides.

Widely used reagent for the Mitsunobu reaction

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves