302937

Perfluoro(methylcyclohexane)

technical grade, 90%

• 동의어(들): (Trifluoromethyl)undecafluorocyclohexane, Perfluoromethylcyclohexane
• Linear Formula: C₆F₁₁CF₃
• CAS Number: 355-02-2
• Molecular Weight: 350.05
• Beilstein: 1915981
• EC Number: 206-573-5
• MDL number: MFCD00001468
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24858283
• NACRES: NA.22

속성

• Grade: technical grade
• Quality Level: 100
• 분석: 90%
• 양식: liquid
• refractive index: n17/D 1.285 (lit.)
• bp: 76 °C (lit.)
• density: 1.787 g/mL at 25 °C (lit.)
• 작용기: fluoro
• SMILES string: FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F
• InChI: 1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12
• InChI key: QIROQPWSJUXOJC-UHFFFAOYSA-N

설명

일반 설명

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.

애플리케이션

Perfluoro(methylcyclohexane) can be used as:

• A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.
• A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.

It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.

Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.

안전성 정보

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves