329576

Sodium trimethylsilanolate

95%

• 동의어(들): Trimethylsilanol sodium salt
• Linear Formula: (CH₃)₃SiONa
• CAS Number: 18027-10-6
• Molecular Weight: 112.18
• Beilstein: 3912148
• EC Number: 241-939-8
• MDL number: MFCD00013926
• UNSPSC 코드: 12352000
• PubChem Substance ID: 24859800
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 95%
• 양식: powder
• mp: 230 °C ((lit.)); 230 °C (dec.) (lit.)
• SMILES string: [[Na+].C[Si](C)(C)[O-]]; [Na+].C[Si](C)(C)[O-]
• InChI: [1S/C3H9OSi.Na/c1-5(2,3)4;/h1-3H3;/q-1;+1]; 1S/C3H9OSi.Na/c1-5(2,3)4;/h1-3H3;/q-1;+1
• InChI key: [HSNUIYJWTSJUMS-UHFFFAOYSA-N]; HSNUIYJWTSJUMS-UHFFFAOYSA-N

설명

일반 설명

Sodium trimethylsilanolate is a versatile and very powerful reagent for the conversion of esters to carboxylic acids and the hydrolysis of nitriles to primary amides. It can be used as a starting material for the synthesis of metal silanolates via the salt metathesis and as a catalyst for the silylation of silanols with hydrosilanes.

애플리케이션

Sodium trimethylsilanolate is used as a catalyst in the:

• Synthesis of the rhodium silonate complex.
• Silylation of methylphenylsilane with tert-butyldimethylsilanol to synthesize trisiloxanes.

안전성 정보

• 픽토그램: GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314
• 예방조치 성명서: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): 230.0 °F - closed cup
• Flash Point (°C): 110 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges