374733

2,6-Diisopropylaniline

97%

• 동의어(들): 2,6-Bis(1-methylethyl)benzenamine, 2,6-Bis(propan-2-yl)aniline, 2,6-Diisopropylphenylamine
• Linear Formula: [(CH₃)₂CH]₂C₆H₃NH₂
• CAS Number: 24544-04-5
• Molecular Weight: 177.29
• Beilstein: 2208763
• EC Number: 246-305-4
• MDL number: MFCD00008887
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24863333
• NACRES: NA.22

속성

• vapor pressure: <0.01 mmHg ( 20 °C)
• Quality Level: 200
• 분석: 97%
• 양식: liquid
• refractive index: n20/D 1.532 (lit.)
• bp: 257 °C (lit.)
• mp: −45 °C (lit.)
• density: 0.94 g/mL at 25 °C (lit.)
• SMILES string: CC(C)c1cccc(C(C)C)c1N
• InChI: 1S/C12H19N/c1-8(2)10-6-5-7-11(9(3)4)12(10)13/h5-9H,13H2,1-4H3
• InChI key: WKBALTUBRZPIPZ-UHFFFAOYSA-N

설명

일반 설명

2,6-Diisopropylaniline is an amine. It undergoes condensation with triacetylmethane in toluene in the presence of p-toluenesulfonic acid provides 3-[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione.

2,6-Diisopropylaniline is an important organic intermediate widely used to synthesize plastics and dyes.

2,6-Diisopropylaniline is an aromatic amine. It reacts with bis(trimethylsilylmethyl)yttrium complexes supported by bulky amidopyridinate (Ap) and amidinate (Amd) ligands to afford yttrium alkyl anilido species. This reaction involves the elimination of TMS (Trimethylsilane).

2,6-Diisopropylaniline is an important organic intermediate widely used to synthesize plastics and dyes.

애플리케이션

2,6-Diisopropylaniline may be used in the preparation of multitopic Schiff-base ligand precursors. It may be used in the preparation of NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene. It may be used to prepare N-heterocyclic carbene complexes for α-arylation of acyclic ketones, amination of haloarenes, and aqueous Suzuki coupling.

2,6-Diisopropylaniline may be used in the preparation of organocatalyst based on naphthalene diimides (NDIs).

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H319,H412
• 예방조치 성명서: P273 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 3 - Eye Irrit. 2
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 2
• 개인 보호 장비: Eyeshields, Gloves