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499617

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide

Name: <I>O</I>-Allyl-<I>N</I>-(9-anthracenylmethyl)cinchonidinium bromide
Brand: ALDRICH

90%

동의어(들):

O(9)-Allyl-N-9-anthracenylcinchonidinium bromide, O(9)-Allyl-N-9-anthracenylmethylcinchonidium bromide, O-Allyl-1-(anthracen-9-ylmethyl)cinchonidinium bromide, O-Allyl-N-(9-anthracenylmethyl)cinchoninium bromide, O-Allyl-N-[(9-anthracenyl)methyl]cinchonidium bromide

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About This Item

실험식(Hill 표기법):

C₃₇H₃₇BrN₂O

CAS Number:

200132-54-3

Molecular Weight:

605.61

MDL number:

MFCD01632446

UNSPSC 코드:

12352005

PubChem Substance ID:

24873293

NACRES:

NA.22

추천 제품

Slide 1 of 10

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Sigma-Aldrich

524433

N-Benzylcinchonidinium bromide

Sigma-Aldrich

C80407

Cinchonidine

Sigma-Aldrich

677086

(11bS)-(+)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide

Sigma-Aldrich

857270

(+)-Cinchonine

Sigma-Aldrich

366188

N-Benzylcinchoninium chloride

Sigma-Aldrich

687596

(11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide

Sigma-Aldrich

374482

N-Benzylquininium chloride

Sigma-Aldrich

392723

(DHQ)₂PHAL

Sigma-Aldrich

418978

(DHQ)₂Pyr

Sigma-Aldrich

218790

Tetraphenylphosphonium chloride

Quality Level

100

분석

90%

광학 활성

[α]20/D −345±30°, c = 0.45 in chloroform

mp

170 °C (dec.) (lit.)

작용기

ether

SMILES string

[Br-].[H][C@@]12CC[N+](C[C@@H]1C=C)(Cc3c4ccccc4cc5ccccc35)[C@@]([H])(C2)[C@H](OCC=C)c6ccnc7ccccc67

InChI

1S/C37H37N2O.BrH/c1-3-21-40-37(33-17-19-38-35-16-10-9-15-32(33)35)36-23-27-18-20-39(36,24-26(27)4-2)25-34-30-13-7-5-11-28(30)22-29-12-6-8-14-31(29)34;/h3-17,19,22,26-27,36-37H,1-2,18,20-21,23-25H2;1H/q+1;/p-1/t26-,27-,36-,37+,39?;/m0./s1

InChI key

QOWNPAUSLGATNL-JNKXQCINSA-M

일반 설명

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide is a cinchona-based chiral phase-transfer catalyst (PTC) that can be used in asymmetric synthesis. It can be prepared from N-(9-anthracenylmethyl)cinchonindinium chloride.

애플리케이션

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide can catalyze the asymmetric alkylation of tert-butyl glycinate-benzophenone Schiff base with different arylmethyl bromides in a micellar medium.