538507

2-Amino-6-bromobenzothiazole

97%

• 실험식(Hill 표기법): C₇H₅BrN₂S
• CAS Number: 15864-32-1
• Molecular Weight: 229.10
• MDL number: MFCD00152229
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24878338
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: solid
• mp: 213-217 °C (lit.)
• 작용기: bromo
• SMILES string: Nc1nc2ccc(Br)cc2s1
• InChI: 1S/C7H5BrN2S/c8-4-1-2-5-6(3-4)11-7(9)10-5/h1-3H,(H2,9,10)
• InChI key: VZEBSJIOUMDNLY-UHFFFAOYSA-N

설명

일반 설명

Reaction of 4-bromoaniline with acetic acid and potassium thiocynate in solution of bromine in acetic acid yields 2-amino-6-bromobenzothiazole. 2-Amino-6-bromobenzothiazole can also be synthesized from 2-aminobenzothiazole via monobromination with silica-supported quinolinium tribromide.

애플리케이션

2-Amino-6-bromobenzothiazole may be used in the synthesis of the following

• 2-amino-6-arylbenzothiazole compounds:
• 6-p-tolylbenzo[d]thiazole-2-amine
• 6-(4chlorophenyl)benzo[d]thiazole-2-amine
• 6-(4-methoxyphenyl)benzo[d]thiazole-2-amine
• 6-(3,5-bis(triflouromethyl)phenyl)benzo[d]thiazole-2-amine
• 6-phenylbenzo[d]thiazole-2-amine

It may be employed as a ligand (L) in the synthesis of organometallic derivatives of Rh(I) [Rh(CO)₂(L)(Cl)].

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H302,H317,H319
• 예방조치 성명서: P261 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Sens. 1
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Faceshields, Gloves