680990

1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene

• 동의어(들): R,R-Et-Ferrocelane^™
• 실험식(Hill 표기법): C₂₆H₄₀FeP₂
• CAS Number: 147762-89-8
• Molecular Weight: 470.39
• MDL number: MFCD09265149
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24885607
• NACRES: NA.22

속성

• 양식: solid
• Quality Level: 100
• 광학 활성: [α]20/D +380°, c = 1 in chloroform
• mp: 85-91 °C
• 작용기: phosphine
• SMILES string: C[Fe]C.CC[C@@H]1CC[C@@H](CC)P1[C@@H]2CCCC2.CC[C@@H]3CC[C@@H](CC)P3[C@H]4CCCC4
• InChI: 1S/2C13H25P.2CH3.Fe/c2*1-3-11-9-10-12(4-2)14(11)13-7-5-6-8-13;;;/h2*11-13H,3-10H2,1-2H3;2*1H3;/t2*11-,12-;;;/m11.../s1
• InChI key: CPUKIDAUDCWIRT-QULUYMGFSA-N

설명

애플리케이션

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene can be used:

• As a catalyst in the asymmetric hydrogenation reactions of olefins and ketones.
• As a component of a rhodium based precatalyst, applicable in the 2-methylenesuccinamic acid hydrogenation reaction.

법적 정보

Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Ferrocelane is a trademark of Kanata Chemical Technologies, Inc.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable