775118

Borane dimethyl sulfide complex solution

1.0 M in 2-methyltetrahydrofuran

• 동의어(들): BMS, Trihydro[thiobis[methane]]boron
• Linear Formula: (CH₃)₂S · BH₃
• CAS Number: 13292-87-0
• Molecular Weight: 75.97
• Beilstein: 3663489
• MDL number: MFCD00013189
• UNSPSC 코드: 12352112
• PubChem Substance ID: 329767736
• NACRES: NA.22

속성

• 양식: liquid
• Quality Level: 100
• 반응 적합성: reagent type: reductant
• 환경친화적 대안 제품 특성: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 농도: 1.0 M in 2-methyltetrahydrofuran
• density: 0.844 g/mL at 25 °C
• 작용기: thioether
• 환경친화적 대안 카테고리: , Aligned
• 저장 온도: 2-8°C
• SMILES string: B.CSC
• InChI: 1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3
• InChI key: RMHDLBZYPISZOI-UHFFFAOYSA-N

설명

일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

애플리케이션

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Commonly used in hydroboration of olefins and as a reductant of carbonyls. 2-Me-THF has shown potential as an environmentally friendly solvent compared to commonly used solvents; e.g. dichloromethane and THF.

For an alternative to Tetrahydrofuran and Dichloromethane, please see: An alternative to Tetrahydrofuran and Dichloromethane

Reactant used as a regioselective reducing agent

Reactant involved in:

• Hydroboration / oxidation

Synthesis of cage compounds

포장

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

법적 정보

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H260,H302,H315,H318,H360FD
• 예방조치 성명서: P210 - P231 + P232 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - Water-react 1
• 보충제 위험성: EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 2
• Flash Point (°F): 9.3 °F
• Flash Point (°C): -12.6 °C