905917

(Ir[Me(Me)ppy]₂(dtbpy))PF₆

• 동의어(들): 4,4′-Bis(t-butyl-2,2′-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, Ir(dmppy)₂(dtbbpy)PF₆
• 실험식(Hill 표기법): C₄₄H₄₈F₆IrN₄P
• CAS Number: 1607469-49-7
• Molecular Weight: 970.06
• MDL number: MFCD31707652
• UNSPSC 코드: 12161600
• NACRES: NA.22

속성

• 양식: powder
• 반응 적합성: core: iridium; reagent type: catalyst; reaction type: Photocatalysis
• 광촉매 활성화: 465 nm
• SMILES string: F[P-](F)(F)(F)(F)F.CC1=CC([Ir+]([N]2=C3C=C(C)C=C2)(C4=C5C=CC(C)=C4)([N]6=C7C=C(C(C)(C)C)C=C6)([N]8=C7C=C(C(C)(C)C)C=C8)[N]9=C5C=C(C)C=C9)=C3C=C1

설명

애플리케이션

(Ir[Me(Me)ppy]₂(dtbpy))PF₆ or Ir(dmppy)₂(dtbbpy)PF₆ is an iridium photoredox catalyst that facilitates a variety of transformations using visible light, including the α- and β-alkylation of aldehydes.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

기타 정보

Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis

Direct, enantioselective α-alkylation of aldehydes using simple olefins

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable