910724

PhPAd-DalPhos

≥95%

• 동의어(들): 8-(2-(Diphenylphosphaneyl)phenyl)-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane
• 실험식(Hill 표기법): C₂₈H₃₀O₃P₂
• CAS Number: 1902911-39-0
• Molecular Weight: 476.48
• MDL number: MFCD32857531
• UNSPSC 코드: 12352002
• NACRES: NA.22

속성

• 분석: ≥95%
• 양식: powder
• 반응 적합성: reagent type: ligand
• mp: 193-194 °C
• 작용기: phosphine
• SMILES string: P4(C5(OC6(OC(OC4(C6)C)(C5)C)C)C)c1c(cccc1)P(c3ccccc3)c2ccccc2
• InChI: 1S/C28H30O3P2/c1-25-19-27(3)31-26(2,29-25)20-28(4,30-25)33(27)24-18-12-11-17-23(24)32(21-13-7-5-8-14-21)22-15-9-6-10-16-22/h5-18H,19-20H2,1-4H3
• InChI key: SWSJANGQMCPBHH-UHFFFAOYSA-N

설명

애플리케이션

PhPAd-DalPhos is ligand developed in the Stradiotto lab that when combined with a Ni(II) source forms an air stable precatalyst for cross coupling of aryl electrophiles with bulky primary amines.

기타 정보

Technology Spotlight: DalPhos ligands

Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design

PhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines

안전성 정보

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable