209198

Copper(II) sulfate pentahydrate

ACS reagent, ≥98.0%

• 동의어(들): Cupric sulfate pentahydrate, Sulfuric acid, copper(II) salt (1:1) pentahydrate
• Linear Formula: CuSO₄ · 5H₂O
• CAS Number: 7758-99-8
• Molecular Weight: 249.69
• EC Number: 231-847-6
• MDL number: MFCD00149681
• UNSPSC 코드: 12352302
• PubChem Substance ID: 329752057
• NACRES: NA.21

속성

• Grade: ACS reagent
• Quality Level: 200
• vapor pressure: 7.3 mmHg ( 25 °C)
• 분석: ≥98.0%; 98.0-102.0% (ACS specification)
• 양식: crystals
• 반응 적합성: reaction type: click chemistry; reagent type: catalyst; core: copper
• pH: 3.5-4.5 (20 °C, 50 g/L)
• mp: 110 °C (dec.) (lit.)
• 음이온 미량물: chloride (Cl^-): ≤0.001%
• 양이온 미량물: Ca: ≤0.005%; Fe: ≤0.003%; K: ≤0.01%; Na: ≤0.02%; Ni: ≤0.005%
• SMILES string: O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O
• InChI: 1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2
• InChI key: JZCCFEFSEZPSOG-UHFFFAOYSA-L

설명

일반 설명

Copper(II) sulfate pentahydrate is a Lewis acid catalyst commonly used to promote acid-catalyzed organic transformations. It can also act as an effective redox catalyst in combination with other mixed oxidizing agents.

애플리케이션

Copper(II) sulfate pentahydrate can be used as a catalyst:      

• In acetylation of alcohols and phenols in the presence of acetic anhydride.      
• To synthesize various ynamides via intramolecular coupling of amides with alkynyl bromides.

It can also be used as a template in the synthesis of copper(II) ion-imprinted polymers using vinylpyridine and methacrylic acid as functional monomers. This polymer is used to quantify Cu²⁺ ion by using flame atomic absorption spectroscopy.

특징 및 장점

CuSO₄.5H₂O is an inexpensive, safe catalyst to be used in various organic transformations. It can also be recovered and reused in another reaction.

안전성 정보

• 픽토그램: GHS05,GHS07,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H302,H318,H410
• 예방조치 성명서: P264 - P273 - P280 - P301 + P312 - P305 + P351 + P338 - P391
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable