249866

Titanium(IV) chloride solution

1.0 M in methylene chloride

• 동의어(들): Titanium tetrachloride
• Linear Formula: TiCl₄
• CAS Number: 7550-45-0
• Molecular Weight: 189.68
• MDL number: MFCD00011267
• UNSPSC 코드: 12352300
• PubChem Substance ID: 329752763
• NACRES: NA.55

속성

• vapor pressure: 24.09 psi ( 55 °C); 6.93 psi ( 20 °C)
• Quality Level: 100
• 양식: liquid
• 반응 적합성: reagent type: catalyst; core: titanium
• 농도: 0.95-1.10 M NaOH (titration); 1.0 M in methylene chloride
• density: 1.365 g/mL at 25 °C
• SMILES string: Cl[Ti](Cl)(Cl)Cl
• InChI: 1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
• InChI key: XJDNKRIXUMDJCW-UHFFFAOYSA-J

설명

일반 설명

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl₄ having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.

애플리케이션

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.

안전성 정보

• 픽토그램: GHS06,GHS08,GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314,H331,H336,H351
• 예방조치 성명서: P202 - P261 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Central nervous system
• 보충제 위험성: EUH014
• Storage Class Code: 6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 2
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable