P7875

Periodic acid

ReagentPlus^®, ≥99.0%

• 실험식(Hill 표기법): H₅IO₆
• CAS Number: 10450-60-9
• Molecular Weight: 227.94
• EC Number: 233-937-0
• MDL number: MFCD00011344
• UNSPSC 코드: 12352106
• PubChem Substance ID: 329820319
• NACRES: NA.21

속성

• Quality Level: 100
• 제품 라인: ReagentPlus^®
• 분석: ≥99.0%
• 양식: powder or crystals
• 반응 적합성: reagent type: oxidant
• 기술: toxicology assay: suitable
• mp: 122 °C (lit.)
• solubility: water: 100 mg/mL, clear, colorless
• SMILES string: OI(O)(O)(O)(O)=O
• InChI: 1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)
• InChI key: TWLXDPFBEPBAQB-UHFFFAOYSA-N

설명

일반 설명

Periodic acid, an oxoacid of iodine, is commonly used as a strong oxidizing agent. This inorganic acid is soluble in most solvents including water and ether.

애플리케이션

Periodic acid can be used in the following reactions:      

• Oxidation of alcohols to ketones and aldehydes.
• Oxidation hydroxylamine derivatives.    
• Oxidation of arenes to quinones.

It can also be used:     

• As a stoichiometric oxidant with chromium (IV) acetate for the oxidation of tertiary C−H bonds to tertiary alcohols.     
• In combination with chromium oxide to oxidize primary alcohols to carboxylic acids; alkylbenzenes to benzoic acids; and cyclic benzyl ethers to the corresponding lactones.      
• In the selective oxidation of sulfides to sulfoxides using FeCl₃ as a catalyst.

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

안전성 정보

• 픽토그램: GHS03,GHS08,GHS05,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H271,H314,H372,H410
• 예방조치 성명서: P210 - P260 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1B - STOT RE 1 Oral
• 표적 기관: Thyroid
• Storage Class Code: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable