106518

Dodecahydrotriphenylene

99%

• Empirical Formula (Hill Notation): C₁₈H₂₄
• CAS Number: 1610-39-5
• Molecular Weight: 240.38
• Beilstein: 2051002
• EC Number: 216-550-1
• MDL number: MFCD00001109
• UNSPSC Code: 12352100
• PubChem Substance ID: 24846736
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 99%
• form: solid
• mp: 231-233 °C (lit.)
• solubility: hexane: soluble
• SMILES string: C1CCc2c(C1)c3CCCCc3c4CCCCc24
• InChI: 1S/C18H24/c1-2-8-14-13(7-1)15-9-3-4-11-17(15)18-12-6-5-10-16(14)18/h1-12H2
• InChI key: ODHYDPYRIQKHCI-UHFFFAOYSA-N

Description

General description

Dodecahydrotriphenylene forms metal-carbonyl complexes. It undergoes hydrogenation and rearrangement by action of AlCl₃ in inert atmosphere conditions at 20°C (hexane solution) or 70°C (heptane solution). It is formed by trimerization of cyclohexanone. It undergoes oxidation by peroxytrifluoroacetic acid and boron fluoride etherate at 0°C to form cross-conjugated cyclohexadieone.

Application

Dodecahydrotriphenylene was used to develop a set of new bacterial bioreporters and assays for detection of long chain alkanes based on the marine bacterium Alcanivorax borkumensis strain SK2.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves