238414
1,3-Diiodopropane
99%, contains copper as stabilizer
Synonym(s):
Trimethylene diiodide
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About This Item
Linear Formula:
I(CH2)3I
CAS Number:
Molecular Weight:
295.89
Beilstein:
1731117
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.642 (lit.)
bp
111-113 °C/31 mmHg (lit.)
density
2.576 g/mL at 25 °C (lit.)
functional group
iodo
storage temp.
2-8°C
SMILES string
ICCCI
InChI
1S/C3H6I2/c4-2-1-3-5/h1-3H2
InChI key
AAAXMNYUNVCMCJ-UHFFFAOYSA-N
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General description
The adsorption of 1,3-diiodopropane on a molybdenum-aluminum alloy thin film formed on dehydroxylated alumina has been studied.
Application
1,3-Diiodopropane has been used in the preparation of synthetically challenging bridged 1,2,4,5-tetraoxanes.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
235.4 °F - closed cup
Flash Point(C)
113 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Gemma L Ellis et al.
Bioorganic & medicinal chemistry letters, 18(5), 1720-1724 (2008-02-05)
Here we present an efficient route into synthetically challenging bridged 1,2,4,5-tetraoxanes. The key to the success of this route is the use of H(2)O(2) and catalytic I(2) to form the gem-dihydroperoxide followed by a Ag(2)O mediated alkylation using 1,3-diiodopropane. Using
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