280704

Sodium tert-pentoxide

95%

• Synonym(s): NaOt-Am, tert-Amyl alcohol sodium salt, Sodium tert-amoxide
• Linear Formula: NaOC(CH₃)₂CH₂CH₃
• CAS Number: 14593-46-5
• Molecular Weight: 110.13
• Beilstein: 3983987
• EC Number: 238-639-4
• MDL number: MFCD00064245
• UNSPSC Code: 12352001
• PubChem Substance ID: 24856952
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 95%
• SMILES string: [Na+].CCC(C)(C)[O-]
• InChI: 1S/C5H11O.Na/c1-4-5(2,3)6;/h4H2,1-3H3;/q-1;+1
• InChI key: CGRKYEALWSRNJS-UHFFFAOYSA-N

Description

Application

Sodium tert-pentoxide (NaOt-Am) is a commonly used base in the deoxycyanamidation of alcohols and in the N-cyanation of secondary amines. It can also be used in the preparation of complex reducing agents to reduce 1-halonaphthalenes and substituted halobenzenes to corresponding naphthalenes and benzenes.

Safety Information

• Pictograms: GHS02,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H228,H251,H312 + H332,H314,H335
• Precautionary Statements: P210 - P235 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 4.2 - Pyrophoric and self-heating hazardous materials
• WGK: WGK 1
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves