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Key Documents

377384

Sigma-Aldrich

Tetraamminepalladium(II) nitrate solution

10 wt. % in H2O

Synonym(s):

Tetraamminedinitratopalladium, Tetraamminepalladium dinitrate

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About This Item

Linear Formula:
Pd(NH3)4(NO3)2
CAS Number:
Molecular Weight:
298.55
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

concentration

10 wt. % in H2O

refractive index

n20/D 1.348

density

1.04 g/mL at 25 °C

SMILES string

N.N.N.N.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.4H3N.Pd/c2*2-1(3)4;;;;;/h;;4*1H3;/q2*-1;;;;;+2

InChI key

WIDMMNCAAAYGKW-UHFFFAOYSA-N

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Application

Precursor to heterogeneous platinum catalysts for isomerizing unfunctionalized alkanes.
Used to prepare a Pd/TS-1 catalyst for the in situ generation of H2O2 and subsequent oxidation of propylene to propylene oxide.

Pictograms

Flame over circleExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Ox. Liq. 2 - Skin Irrit. 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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