387797

4-Bromo-N,N-bis(trimethylsilyl)aniline

97%

• Linear Formula: BrC₆H₄N[Si(CH₃)₃]₂
• CAS Number: 5089-33-8
• Molecular Weight: 316.38
• MDL number: MFCD00191840
• UNSPSC Code: 12352100
• PubChem Substance ID: 24864187
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 97%
• form: liquid
• bp: 156-158 °C/23 mmHg (lit.)
• density: 1.121 g/mL at 25 °C (lit.)
• functional group: bromo
• SMILES string: C[Si](C)(C)N(c1ccc(Br)cc1)[Si](C)(C)C
• InChI: 1S/C12H22BrNSi2/c1-15(2,3)14(16(4,5)6)12-9-7-11(13)8-10-12/h7-10H,1-6H3
• InChI key: YJYMZGDBOMZWSR-UHFFFAOYSA-N

Description

Application

4-Bromo-N,N-bis(trimethylsilyl)aniline is an N-protected aryl reagent used in the synthesis of:

• Hydrophilic conjugated porphyrin dimers for one-photon and two-photon photodynamic therapy.
• Functionalized organometallic polymer, poly(ferrocenylsilane).
• Borylanilines such as 4-(dimesitylboryl)aniline and 4-(dimesitylboryl)-3,5-dimethylaniline.
• Silicon-containing oligomeric poly(imido-amides) (PIAs).

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 235.4 °F - closed cup
• Flash Point(C): 113 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves