437867
Copper(II) bromide
99.999% trace metals basis
Synonym(s):
Cupric bromide
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About This Item
Linear Formula:
CuBr2
CAS Number:
Molecular Weight:
223.35
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
form:
solid
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Quality Level
Assay
99.999% trace metals basis
form
solid
reaction suitability
core: copper
impurities
≤15.0 ppm Trace Metal Analysis
mp
498 °C (lit.)
density
4.77 g/mL at 25 °C (lit.)
SMILES string
Br[Cu]Br
InChI
1S/2BrH.Cu/h2*1H;/q;;+2/p-2
InChI key
QTMDXZNDVAMKGV-UHFFFAOYSA-L
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General description
Copper bromide is a monoclinic crystalline material. It is soluble in water, alcohol and acetone. It may be synthesized by neutralizing oxides, carbonates or hydroxides of copper with hydrobromic acid. Another synthesis technique is by oxidizing copper either with bromine water or bromine solutions in alcohol.
Application
Copper bromide may be used as a catalyst in organic reactions and as a brominating agent. Copper catalyzed biotinylation of acetylene terminated poly(ethylene glycol) methyl ether methylacrylate (PEGMEMA) chains has been investigated. Copper dibromide in acetonitrile acts as a catalyst in the interconversion of acetals to bis(methoxyphenyl)methyl (BMPM) ethers. It has been used as a catalyst in the intramolecular decarboxylative functionalization of α-carbonyl to yield a C(sp(3))-O bond for the synthesis of furo[3,2-c]coumarins. Poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been reportedly doped with CuBr2 to act as hole transport layer (HTL) in polymer solar cells(PSCs). Doping increase the conductivity and thereby increasing the device power conversion efficiency of PSCs.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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