559091

Ethyl (2-chlorobenzoyl)acetate

≥95%

• Synonym(s): Ethyl (o-chlorobenzoyl)acetate, Ethyl 3-(2-chlorophenyl)-3-oxopropanoate, NSC 158136
• Linear Formula: ClC₆H₄COCH₂CO₂C₂H₅
• CAS Number: 19112-35-7
• Molecular Weight: 226.66
• MDL number: MFCD03424811
• UNSPSC Code: 12352100
• PubChem Substance ID: 24879794
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: ≥95%
• refractive index: n20/D 1.540 (lit.)
• bp: 221-222 °C (lit.)
• density: 1.206 g/mL at 25 °C (lit.)
• functional group: chloro; ester; ketone
• SMILES string: CCOC(=O)CC(=O)c1ccccc1Cl
• InChI: 1S/C11H11ClO3/c1-2-15-11(14)7-10(13)8-5-3-4-6-9(8)12/h3-6H,2,7H2,1H3
• InChI key: DLFBNTUSDQSFOF-UHFFFAOYSA-N

Description

Application

Ethyl (2-chlorobenzoyl)acetate may be used to synthesize ketosplitomicin derivative and ethyl 6-(2-chlorophenyl)-2,2-dimethyl-4-oxo-2,3-dihydro-4Hpyran-5-carboxylate.

Reactant for:

• Cerium ammonium nitrate-mediated oxidative coupling
• Hydrosilylation reactions
• Preparation of diaryl-substituted pyrazoles as potent CCR2 receptor antagonists
• Preparation of potential herbicidal agents
• Ruthenium-catalyzed asymmetric hydrogenation

Safety Information

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves