561657
(1,3-Dioxan-2-ylethyl)magnesium bromide solution
0.5 M in THF
Synonym(s):
1,3-Dioxane - 2-ethyl- magnesium complex, [2-(1,3-Dioxan-2-yl)ethyl]magnesium bromide
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About This Item
Empirical Formula (Hill Notation):
C6H11BrMgO2
CAS Number:
Molecular Weight:
219.36
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
reaction suitability
reaction type: Grignard Reaction
Quality Level
concentration
0.5 M in THF
bp
65 °C
density
0.951 g/mL at 25 °C
functional group
ether
storage temp.
2-8°C
SMILES string
Br[Mg]CCC1OCCCO1
InChI
1S/C6H11O2.BrH.Mg/c1-2-6-7-4-3-5-8-6;;/h6H,1-5H2;1H;/q;;+1/p-1
InChI key
JYNXRXBIEHSSLR-UHFFFAOYSA-M
Application
(1,3-Dioxan-2-ylethyl)magnesium bromide can be used:
- In a Grignard addition-acylation method for the preparation of enamides.
- To prepare trisubstituted allenes by reacting with propargylic ammonium salts.
- In one of the key synthetic steps for the synthesis of febrifugine based antimalarial drugs.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
No data available
Flash Point(C)
No data available
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