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689785

Sigma-Aldrich

(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

greener alternative

≥97.0% (qNMR)

Synonym(s):

(11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-bi-2-naphthol cyclic monophosphate, (S)-TRIP

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3 X 1.5 ML
RM 479.08

About This Item

Empirical Formula (Hill Notation):
C50H57O4P
CAS Number:
Molecular Weight:
752.96
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

RM 479.08


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Quality Level

Assay

≥97.0% (qNMR)

form

lumps

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

functional group

phosphate

greener alternative category

SMILES string

CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2cc3ccccc3c-4c2OP(O)(=O)Oc5c(cc6ccccc6c-45)-c7c(cc(cc7C(C)C)C(C)C)C(C)C

InChI

1S/C50H57O4P/c1-27(2)35-23-39(29(5)6)45(40(24-35)30(7)8)43-21-33-17-13-15-19-37(33)47-48-38-20-16-14-18-34(38)22-44(50(48)54-55(51,52)53-49(43)47)46-41(31(9)10)25-36(28(3)4)26-42(46)32(11)12/h13-32H,1-12H3,(H,51,52)

InChI key

AGQAQYPGJDBIQR-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.

Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

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This Item
SAB4701030SAB4701012SAB4500087
antibody form

affinity isolated antibody

antibody form

purified immunoglobulin

antibody form

purified immunoglobulin

antibody form

affinity isolated antibody

Quality Level

100

Quality Level

-

Quality Level

-

Quality Level

100

conjugate

unconjugated

conjugate

unconjugated

conjugate

unconjugated

conjugate

unconjugated

biological source

rabbit

biological source

mouse

biological source

mouse

biological source

rabbit

storage temp.

−20°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

−20°C

mol wt

antigen 51 kDa

mol wt

-

mol wt

-

mol wt

antigen 50 kDa


Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves


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    Butyl methyl ether; Acetic acid; 2-Butanone; Ethyl acetate; Tetrahydrofuran; 1-Butanol; Isopropyl acetate; Heptane; Propyl acetate; 3-Methylbutanol; 4-Methyl-2-pentanone; Isobutyl acetate; Butyl acetate; Dimethyl sulfoxide; Anisole; Cumene

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    Analytical Chemistry, 39(13), 1652-1654 (1967)