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90350

Sigma-Aldrich

Triethylamine hydrochloride

≥99.0% (AT)

Synonym(s):

N,N-Diethylethanamine hydrochloride, Triethylamine monohydrochloride, Triethylammonium chloride

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About This Item

Linear Formula:
(C2H5)3N · HCl
CAS Number:
Molecular Weight:
137.65
Beilstein:
3906409
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

≥99.0% (AT)

form

crystals

mp

261 °C (dec.) (lit.)

solubility

water: soluble 1 g/10 mL

functional group

amine

SMILES string

Cl.CCN(CC)CC

InChI

1S/C6H15N.ClH/c1-4-7(5-2)6-3;/h4-6H2,1-3H3;1H

InChI key

ILWRPSCZWQJDMK-UHFFFAOYSA-N

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General description

Triethylamine hydrochloride can be used as a:
  • Catalyst to synthesize diphenylmethane via Friedel-Crafts reaction of benzene with benzyl chloride.
  • Reactant in the ionic liquid-catalyzed synthesis of quaternary ammonium salts with dialkyl carbonates.
It can also be used as a proton donor:
  • For the titanocene (III)-catalyzed intramolecular ring-opening arylation of epoxides.
  • In intramolecular Kinugasa reaction to synthesize β-lactams.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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