90350

Triethylamine hydrochloride

≥99.0% (AT)

• Synonym(s): N,N-Diethylethanamine hydrochloride, Triethylamine monohydrochloride, Triethylammonium chloride
• Linear Formula: (C₂H₅)₃N · HCl
• CAS Number: 554-68-7
• Molecular Weight: 137.65
• Beilstein: 3906409
• EC Number: 209-067-2
• MDL number: MFCD00012500
• UNSPSC Code: 12352100
• PubChem Substance ID: 57653388
• NACRES: NA.22

Properties

• Assay: ≥99.0% (AT)
• form: crystals
• mp: 261 °C (dec.) (lit.)
• solubility: water: soluble 1 g/10 mL
• functional group: amine
• SMILES string: Cl.CCN(CC)CC
• InChI: 1S/C6H15N.ClH/c1-4-7(5-2)6-3;/h4-6H2,1-3H3;1H
• InChI key: ILWRPSCZWQJDMK-UHFFFAOYSA-N

Description

General description

Triethylamine hydrochloride can be used as a:

• Catalyst to synthesize diphenylmethane via Friedel-Crafts reaction of benzene with benzyl chloride.
• Reactant in the ionic liquid-catalyzed synthesis of quaternary ammonium salts with dialkyl carbonates.

It can also be used as a proton donor:

• For the titanocene (III)-catalyzed intramolecular ring-opening arylation of epoxides.
• In intramolecular Kinugasa reaction to synthesize β-lactams.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315 - H319 - H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves