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905542

Sigma-Aldrich

(R,R)-SINpEt⋅HBF4

≥95%

Synonym(s):

1,3-Bis((R)-1-(naphthalen-1-yl)ethyl)-4,5-dihydro-1H-imidazol-3-ium tetrafluoroborate

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About This Item

Empirical Formula (Hill Notation):
C27H27BF4N2
CAS Number:
Molecular Weight:
466.32
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22

Assay

≥95%

form

powder or crystals

reaction suitability

reagent type: ligand

functional group

phosphine

storage temp.

2-8°C

SMILES string

[B-](F)(F)(F)F.[N+]3(=CN(CC3)[C@H](C)c4c5c(ccc4)cccc5)[C@H](C)c1c2c(ccc1)cccc2

InChI key

VYIDGCVFAXSDII-MUCZFFFMSA-N

Application

(R,R)-SINpEt⋅HBF4 is a chiral NHC ligand developed in the Glorius Lab for use in Ru(II) catalyzed enantioselective hydrogenations. It has been employed for the regioselectivity asymmetric hydrogenation of quinoxalines, benzofurans, thiophenes, indolizines, isocoumarins and many other heterocycles.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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