905542

(R,R)-SINpEt⋅HBF₄

≥95%

• Synonym(s): 1,3-Bis((R)-1-(naphthalen-1-yl)ethyl)-4,5-dihydro-1H-imidazol-3-ium tetrafluoroborate
• Empirical Formula (Hill Notation): C₂₇H₂₇BF₄N₂
• CAS Number: 1344155-18-5
• Molecular Weight: 466.32
• MDL number: MFCD32197455
• UNSPSC Code: 12352101
• NACRES: NA.22

Properties

• Assay: ≥95%
• form: powder or crystals
• reaction suitability: reagent type: ligand
• functional group: phosphine
• storage temp.: 2-8°C
• SMILES string: [B-](F)(F)(F)F.[N+]3(=CN(CC3)[C@H](C)c4c5c(ccc4)cccc5)[C@H](C)c1c2c(ccc1)cccc2
• InChI key: VYIDGCVFAXSDII-MUCZFFFMSA-N

Description

Application

(R,R)-SINpEt⋅HBF₄ is a chiral NHC ligand developed in the Glorius Lab for use in Ru(II) catalyzed enantioselective hydrogenations. It has been employed for the regioselectivity asymmetric hydrogenation of quinoxalines, benzofurans, thiophenes, indolizines, isocoumarins and many other heterocycles.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Other Notes

Ligand-Controlled Highly Regioselective and Asymmetric Hydrogenation of Quinoxalines Catalyzed by Ruthenium N-Heterocyclic Carbene Complexes

Ruthenium–NHC–Diamine Catalyzed Enantioselective Hydrogenation of Isocoumarins

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable