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934542

Sigma-Aldrich

Silyl-ether based ROMP Monomer

PhSi

Synonym(s):

2,2-Diphenyl-1,3-dioxa-2-silacyclooct-5-ene

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About This Item

Empirical Formula (Hill Notation):
C17H18O2Si
CAS Number:
Molecular Weight:
282.41
UNSPSC Code:
12162002
NACRES:
NA.21

Assay

≥98%

Quality Level

form

powder or crystals

composition

PhSi

color

off-white to light yellow

SMILES string

C1([Si]2(C3=CC=CC=C3)OC/C=C\CCO2)=CC=CC=C1

InChI key

AVFOQRQHJSIDGD-BAQGIRSFSA-N

General description

Ring opening metathesis polymerization (ROMP) monomers are attractive building block for advanced polymeric materials in the biomedical field. 2,2-Diphenyl-1,3-dioxa-2-silacyclooct-5-ene, or the silyl ether based ROMP monomer PhSi, is a bifunctional cyclic olefin that can be used to synthesize a variety of macromolecules and polymers with diverse compositions and complex structures. PhSi can copolymerize with a variety of norbornene derivatives including small molecules and macromolecules, enabling the formation of backbone-degradable copolymers that can be used in a variety of biomedical applications. The ROMP polymerization method is superior as it permits the tailorability of the resulting polymer material.

Application

Synthesis of advanced polymeric materials for biomedical applications including:
  • drug delivery
  • molecular imaging
  • self assembly
  • hydrogels
  • medical device coatings
  • stimuli responsive material

Features and Benefits

  • Copolymerize efficiency with a wide variety of norbornene-based (macro)monomers
  • Controlled ROMP polymerization
  • Silyl ether substitute can be tuned to control degradation

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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