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ALD00004

Sigma-Aldrich

Li-Yu t-Butyl Quinoline

95%

Synonym(s):

3,4-Dihydro-7-tert-butyl-2,5-dimethyl-2H-pyrano[2,3-b]quinoline

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About This Item

Empirical Formula (Hill Notation):
C18H23NO
Molecular Weight:
269.38
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
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Quality Level

Assay

95%

form

solid

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

mp

202-207 °C

SMILES string

CC1=C2C(OC(C)CC2)=NC3=C1C=C(C(C)(C)C)C=C3

InChI

1S/C18H23NO/c1-11-6-8-14-12(2)15-10-13(18(3,4)5)7-9-16(15)19-17(14)20-11/h7,9-11H,6,8H2,1-5H3

InChI key

HGKGTNXPFXRVQB-UHFFFAOYSA-N

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This Item
541601G541602C141101P
shipped in

dry ice

shipped in

dry ice

shipped in

dry ice

shipped in

dry ice

packaging

pkg of 1 × 1 g (541602P-1g), pkg of 5 × 100 mg (541602P-500mg), pkg of 1 × 100 mg (541602P-100mg)

packaging

pkg of 1 × 50 g (541601G-50g)

packaging

pkg of 2 × 20 mL (541602C-1g), pkg of 1 × 4 mL (541602C-100mg), pkg of 5 × 4 mL (541602C-500mg)

packaging

pkg of 1 × 100 mg (141101P-100mg), pkg of 5 × 100 mg (141101P-500mg)

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

form

powder

form

granular

form

chloroform solution

form

powder

manufacturer/tradename

Avanti Research - A Croda Brand

manufacturer/tradename

Avanti Research - A Croda Brand

manufacturer/tradename

Avanti Research - A Croda Brand

manufacturer/tradename

Avanti Research - A Croda Brand

lipid type

lipid extracts

lipid type

phosphoglycerides
phospholipids

lipid type

lipid extracts

lipid type

lipid extracts

Application

Ligand is optimal for gamma C-H functionalization of aliphatic acids through Pd-catalyzed C-H activation. The Yu group has demonstrated a variety of transformations, such as olefination, carbonylation, and arylation.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Tao Yu et al.
Cell, 174(6), 1549-1558 (2018-08-14)
Engineering microorganisms for production of fuels and chemicals often requires major re-programming of metabolism to ensure high flux toward the product of interest. This is challenging, as millions of years of evolution have resulted in establishment of tight regulation of
Gauri S Joshi et al.
Journal of bacteriology, 194(6), 1350-1360 (2012-01-17)
The cbb(I) region of Rhodopseudomonas palustris (Rp. palustris) contains the cbbLS genes encoding form I ribulose-1,5-bisphosphate (RuBP) carboxylase oxygenase (RubisCO) along with a divergently transcribed regulator gene, cbbR. Juxtaposed between cbbR and cbbLS are the cbbRRS genes, encoding an unusual
Guilherme Vargas Bochi et al.
Inflammation, 35(6), 1786-1792 (2012-07-11)
The accumulation of advanced oxidation protein products (AOPP) has been linked to several pathological conditions. Previous studies have identified AOPP as a novel biomarker of oxidative damage to proteins and a novel class of mediator of inflammation. The aim of
Roberto Christ Vianna Santos et al.
Inflammation, 35(3), 1198-1203 (2012-02-14)
It has been previously showed that fructose-1,6-bisphosphate (FBP) has anti-inflammatory and immunomodulatory effects on several experimental inflammation models. However, the effects and mechanism of FBP on Zymosan-induced acute lung injury (ALI) in mice had not been tested. In this study
Chao Qi et al.
Chemistry, an Asian journal, 8(1), 88-94 (2012-11-30)
Calcium phosphates (CPs), as the major inorganic component of biological hard tissues, have been investigated for applications as biomaterials owing to their excellent biocompatibility. However, the traditional synthetic CPs are usually prepared from inorganic phosphorus and calcium sources. Herein, we

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