92337
Bromotrimethylsilane
purum, ≥97.0% (AT)
Synonym(s):
TMBS, Trimethylbromosilane, Trimethylsilyl bromide
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About This Item
Linear Formula:
(CH3)3SiBr
CAS Number:
Molecular Weight:
153.09
Beilstein:
1731135
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
grade
purum
Quality Level
Assay
≥97.0% (AT)
form
liquid
contains
silver wool as stabilizer
refractive index
n20/D 1.424 (lit.)
n20/D 1.424
bp
79 °C (lit.)
density
1.16 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C[Si](C)(C)Br
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General description
Bromotrimethylsilane is used with Cl3 to catalyze the direct allylation of a variety of alcohols with allyltrimethylsilane.
Application
Bromotrimethylsilane may be used as a derivatizing reagent for the determination of alkyl lysophospholipids in cell culture media using gas chromatography technique.
Other Notes
Powerful silylating agent ; Cleavage of ethers ; Smooth cleavage of phosphonic and phosphoric alkyl esters
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
10.4 °F - closed cup
Flash Point(C)
-12 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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