Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

View All Documentation

124087

Sigma-Aldrich

2-Bromo-4-methylaniline

98%

Synonym(s):

2-Bromo-p-toluidine, 4-Amino-3-bromotoluene

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
BrC6H3(CH3)NH2
CAS Number:
583-68-6
Molecular Weight:
186.05
Beilstein/REAXYS Number:
1931711
EC Number:
209-515-7
MDL number:
MFCD00007635
UNSPSC Code:
12352100
PubChem Substance ID:
24847595
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.602 (lit.)

bp

240 °C (lit.)

mp

14-16 °C (lit.)

density

1.5 g/mL at 25 °C (lit.)

functional group

bromo

SMILES string

Cc1ccc(N)c(Br)c1

InChI

1S/C7H8BrN/c1-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3

Looking for similar products? Visit Product Comparison Guide

Related Categories

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
154253480835154261
2-Bromo-4-methylaniline 98%

124087

2-Bromo-4-methylaniline

4-Bromo-2-methylaniline 97%

154253

4-Bromo-2-methylaniline

2-Bromo-4-methylanisole 97%

480835

2-Bromo-4-methylanisole

4-Bromo-3-methylaniline 97%

154261

4-Bromo-3-methylaniline

assay

98%

assay

97%

assay

97%

assay

97%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

form

liquid

form

-

form

-

form

solid

refractive index

n20/D 1.602 (lit.)

refractive index

-

refractive index

n20/D 1.565 (lit.)

refractive index

-

density

1.5 g/mL at 25 °C (lit.)

density

-

density

1.392 g/mL at 25 °C (lit.)

density

-

bp

240 °C (lit.)

bp

240 °C (lit.)

bp

124-125 °C/20 mmHg (lit.)

bp

240 °C (lit.)

General description

2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline[1]. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me3Al to form amide[2].

Application

2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes[3].

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

  • Specification Sheet

    • Choose from one of the most recent versions:

    Certificates of Analysis (COA)

    Lot/Batch Number
    STBC9662V
    S27598V
    07515HH
    11605CH
    19519MD

    Don't see the Right Version?

    If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

    Search for a COA

    Already Own This Product?

    Find documentation for the products that you have recently purchased in the Document Library.

    Visit the Document Library

    Ratios of low molecular weight alkylbenzenes (C0-C4) in Chinese crude oils as indicators of maturity and depositional environment.
    Cheng B, et al.
    Organic Geochemistry, 88, 78-90 (2015)
    New approach to resolve the humidity problem in VOC determination in outdoor air samples using solid adsorbent tubes followed by TD-GC-MS.
    Maceira A, et al.
    The Science of the Total Environment, 599, 1718-1727 (2017)
    Kanji Yamasaki et al.
    Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 50(8), 2635-2642 (2012-05-31)
    The purpose of this study was to investigate the endocrine-mediated effects of the benzene-related compounds with reference to Organization for Economic Co-operation and Development (OECD) Test Guideline No. 407. Rats were orally gavaged with 0, 10, 50, and 250 mg/kg/day
    Prospective application of melanized fungi for the biofiltration of indoor air in closed bioregenerative systems.
    Prenafeta-Boldu FX, et al.
    Journal of Hazardous Materials, 361, 1-9 (2019)
    Determination of odour concentration by TD-GC x GC-TOF-MS and field olfactometry techniques.
    Bylinski H, et al.
    Monatshefte fur Chemie / Chemical Monthly, 148(9), 1651-1659 (2017)
    View All Related Papers

    Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

    Contact Technical Service