145262

(Ethoxycarbonylmethyl)dimethylsulfonium bromide

97%

• Linear Formula: C₂H₅O₂CCH₂S(CH₃)₂Br
• CAS Number: 5187-82-6
• Molecular Weight: 231.15
• EC Number: 225-968-3
• MDL number: MFCD00830557
• UNSPSC Code: 12352100
• PubChem Substance ID: 24848710
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 97%
• form: solid
• mp: 90-94 °C (lit.)
• functional group: ester; thioether
• SMILES string: Br.CCOC(=O)C[S](C)C
• InChI: 1S/C6H13O2S.BrH/c1-4-8-6(7)5-9(2)3;/h4-5H2,1-3H3;1H/q+1;/p-1
• InChI key: JXFPTJYKYKVENJ-UHFFFAOYSA-M

Description

Application

(Ethoxycarbonylmethyl)dimethylsulfonium bromide was used in synthesis of α-sulfanyl-β-amino acid derivatives by using nanocrystalline magnesium oxide. It was used during cyclopropanation of (-)-(S)-2-(p-tolylsulfinyl)cyclopent-2-enone.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves