206113

Platinum(IV) chloride

96%

• Synonym(s): Platinum tetrachloride
• Linear Formula: PtCl₄
• CAS Number: 13454-96-1
• Molecular Weight: 336.89
• EC Number: 236-645-1
• MDL number: MFCD00011182
• UNSPSC Code: 12352302
• eCl@ss: 38191307
• PubChem Substance ID: 24852378
• NACRES: NA.23
• assay: 96%
• form: powder and chunks

Properties

• Quality Level: 100
• assay: 96%
• form: powder and chunks
• reaction suitability: core: platinum; reagent type: catalyst
• mp: 370 °C (dec.) (lit.)
• density: 4.303 g/mL at 25 °C (lit.)
• application(s): PEM fuel cells; homogeneous catalyst; material synthesis precursor
• SMILES string: Cl[Pt](Cl)(Cl)Cl
• InChI: 1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4
• InChI key: FBEIPJNQGITEBL-UHFFFAOYSA-J

Description

Application

Platinum(IV) chloride can be used as a precursor to synthesize Pt-based nanocatalysts for various organic transformations. For example, Carbon-supported Pt-Ru nanoparticles can be used as an efficient catalyst for methanol and ethanol oxidation.

Due to its high affinity to the glycosyl acceptor hydroxy groups and bidentate ligation capacity, it can be used as a dual catalyst for regio- and stereoselective glycosidation reactions.

It can also be used for the photosensitization and surface modification of TiO₂ for the photodegradation of 4-chlorophenol.

Safety Information

• pictograms: GHS06,GHS08,GHS05
• signalword: Danger
• hcodes: H301,H314,H317,H334
• pcodes: P260 - P272 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• wgk_germany: WGK 2
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges