260908

N-Bromophthalimide

95%

• Empirical Formula (Hill Notation): C₈H₄BrNO₂
• CAS Number: 2439-85-2
• Molecular Weight: 226.03
• Beilstein/REAXYS Number: 131211
• EC Number: 219-467-9
• MDL number: MFCD00005888
• UNSPSC Code: 12352100
• PubChem Substance ID: 24855777
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 95%
• mp: 194-198 °C (lit.)
• functional group: imide
• SMILES string: BrN1C(=O)c2ccccc2C1=O
• InChI: 1S/C8H4BrNO2/c9-10-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H
• InChI key: MARXMDRWROUXMD-UHFFFAOYSA-N

Description

Application

N-Bromophthalimide has been used:

• as reagent in allylic amination reactions of alkenes
• brominating reagent in enantioselective synthesis of multisubstituted biaryl derivatives by chiral phosphoric acid catalyzed asymmetric bromination
• as a titrant in titrimetric determination of isoniazid in pure form or in tablets

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves