278688

9-Anthracenecarboxaldehyde

97%

• Synonym(s): 9-Anthraldehyde
• Empirical Formula (Hill Notation): C₁₅H₁₀O
• CAS Number: 642-31-9
• Molecular Weight: 206.24
• Beilstein/REAXYS Number: 639167
• EC Number: 211-383-0
• MDL number: MFCD00001254
• UNSPSC Code: 12352100
• PubChem Substance ID: 24856824
• NACRES: NA.22

Properties

• assay: 97%
• form: solid
• mp: 103-105 °C (lit.)
• functional group: aldehyde
• SMILES string: [H]C(=O)c1c2ccccc2cc3ccccc13
• InChI: 1S/C15H10O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-10H
• InChI key: YMNKUHIVVMFOFO-UHFFFAOYSA-N

Description

General description

The Diels-Alder reaction of 9-anthracenecarboxaldehyde with benzenediazonium-2-carboxylate was studied.

Application

9-Anthracenecarboxaldehyde has been used in the synthesis of:

• new asymmetrical tridentate Schiff base ligands
• 2-(9-anthrylmethyl-ideneamino)-4-methyl-phenol, novel Schiff base via condensation with 2-amino-p-cresol
• functionalized ligand, 2-(anthracen-9-ylidene)-4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione via Knoevenangel condensation with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)