296066

Lithium dimethylamide

95%

• Synonym(s): Lithiodimethylamide
• Linear Formula: (CH₃)₂NLi
• CAS Number: 3585-33-9
• Molecular Weight: 51.02
• Beilstein/REAXYS Number: 3618233
• EC Number: 222-714-3
• MDL number: MFCD00008295
• UNSPSC Code: 12352111
• PubChem Substance ID: 24857832
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 95%
• form: solid
• functional group: amine
• SMILES string: [Li]N(C)C
• InChI: 1S/C2H6N.Li/c1-3-2;/h1-2H3;/q-1;+1
• InChI key: YDGSUPBDGKOGQT-UHFFFAOYSA-N

Description

Application

Lithium dimethylamide is used as a reagent in the synthesis of boron-nitrogen heterocycles and 2,2′?diborabiphenyl. It is a deprotecting agent which is employed in demethylation of bis(imino)pyridine ferrous dichloride for synthesizing ferrous amide-ate complexes.

Safety Information

• pictograms: GHS02,GHS05
• signalword: Danger
• hcodes: H250,H261,H314
• pcodes: P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Pyr. Sol. 1 - Skin Corr. 1B - Water-react 2
• Storage Class: 4.2 - Pyrophoric and self-heating hazardous materials
• wgk_germany: WGK 3
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges